I recall a past post here where Thorn designer Andy Blance spoke to the matter. If I recall correctly, the goal of this placement was to reduce brake judder and squeal by pulling the mounts, brakes, and pads inward under brsking rather than outward as in conventional designs.
I recall seeing some early Thorn-sourced photos that showed cantis mounted on the rearward-facing fork bosses. They were actuated by a Sun Tour bell crank -- a little teeter-totter device. The cable was routed through one side of the bellcrank and secured to one canti brake arm, the bellcrank served as a bedstop for the housing. The other side pulled canti through a short straddle cable. Equal and opposite forces were split evenly between the arms with disconnection as easy as a v-brake. Sometimes, a similar setup is used to actuate rear cantis from below on an open frame.
There are times my good memory is a curse, so here's a truly esoteric bit of trivia that may have inspired Andy's rear-side fork brake boss placement: I can't speak for Andy, but as a longtime roadie and with Robin Thorn starting with bike repairs...
In the early 1970s, road rims were available with flat-sided/"straight"/parallel or angled sidewall designs, where the rim edge was wider than the base. Most sidepull calipers of the day had pretty flexible arms that were pulled forward by the brake pads.
On the rear, when used with angled rims, this had the effect of pulling the pads from the wider to narrower part of the rim, reducing braking. Canny bespoke framebuilders and mechanics would reverse the rear sidepull caliper, mounting it on the forward side of the seatstay brake bridge. Under braking, the pads would be drawn forward and upward into the wider part of the angle-sided rim, creating a mild self-energizing effect and reducing judder and squeal.
I have a couple bikes dating from 1970s originally equipped with angled rims and sidepulls and, yes, there was a noticeably positive difference to reversing the rear brake. I'm guessing such influenced Andy, at least for a time, but of course confirmation would have to come from him.
Whew! Enough historical trivia and esoterica from me for the moment; I'm tapped out!
All the best, Dan.