On my recent tour in the Canadian Maritimes, twice I suspected that something seemed to slip in the Rohloff. Each time, I quit pedaling, changed gears and resumed pedaling and everything was fine.
After that 2nd time, in the evening I pulled out the rear wheel, gave the drive side axle a couple of whacks with a rubber soled shoe, replaced wheel. Then I tightened up the chain which was much looser than I thought it should be.
After that everything was fine.
After reading this post shortly before my trip, I may have been susceptible to thinking that the hub slipped. But I really started to wonder if the internals of the hub had a hiccup or if my chain was too loose? I suspect that the chain just needed tightening.