...Feels like a slack pause when first pushing the pedals...
Wow, a lot of replies. Thanks for the suggestions all.
StillOld's "slack pause" is a very good way to describe this phenomenon.
I have checked cable and chain tension and small adjustments to both made no difference. The rear wheel's skewer is good and tight too. The BB (Phil Wood) seems to be fine even though it's clocked around 15000 miles now, and the cranks are good and tight. Other than the BB all components of the drive train are new so there shouldn't hopefully be an issue with the chain/chainring/sprocket relationship. All conform to Rohloff requirements with regards sizing and ratios.
JimK, your question as to whether this happens right after a gear shift (from standing at lights, say) I cannot answer with confidence and need to check. BUT, I am fairly sure it happens regardless of whether I shift just before or remain in the same gear coming to a stop and then moving away. Will double-check this though. For certain, the phenomenon is ONLY ever experienced (by myself) when pulling away from a stop, never when, say, standing up on pedals and exerting extra torque to the drive train on hills.
geocycle, not sure whether the sprocket is threaded or splined. Is there an easy way to tell just from looking at it still attached to the hub?
Thanks all for the welcome and your replies.