Yes, a Rohloff steel frame touring bike is certainly not equivalent to a carbon race bike like the Madone.
I do not know where you are, but I am guessing (like Dan did) that you are located in USA and do not know of anyone locally that is familiar with Rohloff bikes. I have a neighbor that has been a part time bike mechanic for many years, he has told me that my Rohloff bike is the only one he has ever seen.
If you have not looked at the owner manual yet, you should. If the previous owner did not change the oil in the hub for a while, you should. There is a short video on the internet for instructions on how to do that, not sure the link but a google search will find it. I have found Rohloff oil change kits on Amazon at a reasonably good price. I assume you have figured out how to correctly tension the chain with the eccentric. The oil change kit comes with 25ml of oil, but you only need to put in 15ml.
If your rims are labeled Carbide Super Sonic by Rigida or by Ryde, you need to use special brake pads that I do not know if you can buy anywhere in USA. When I built up my Nomad, I bought spare brake pads, thus I have not tried to source them here. If your rims are not labeled that way, forget I mentioned it, any brake pads should work.
Good luck.