Presta pump more easily, to higher pressure, being designed for intermittent pressure (like a bike pump!), Schraeder apparently designed for constant flow inflation, like an airhose. Most Schraeder valve cores are not interchangeable, as different brands seem to use marginally different shapes and lengths, however valves fail at a minute fraction of the rate that tubes do. I took the cores out of Schraeder valves before throwing dead tubes away, but gave up having never used one.
For expedition touring, using Schraeder-drilled rims with Presta-valved tubes, together with grommet to support the narrower valve makes sense - easy pumping, but you can use cheap, nasty Schraeder- or even Woods-valved tubes in the back of beyond, when your spares can't take more patching, are torn etc.