The adjustment is usually done by loosening the nut holding the brake pad and moving it around until the pad faces the way you want.
I temporarily put a piece of cardboard under the trailing edge of the pad and holding the pad against the rim, tighten the nut up. This gives a bit of toe in which usually avoids brake squeal.
If the brake pad needs to be nearer to, or further from, the rim then swap the thick and thin washers over whilst the nut is off.
If none of this makes sense, then post again and I will put some photos up.
And yes the wheel needs to be true for the best results.