It is not clear to me if this is for a Rohloff bike or derailleur bike with a double/triple?
And if it is for a Rohloff bike, does it have a double crank?
And if it is a double with one chainring on a Rohloff bike, do the chainring bolts have the little spacers that come with the Rohloff that allow you to use the double length bolts with a single chainring on a double crank?
In other words, we can't make firm answers without knowing what the situation is.
For my Nomad (Rohloff) bike which has a double crank, I cut the teeth off a 52T chainring to use as a bashguard with a 44T chainring, thus 8 teeth difference. That was a bit bigger than it needed to be but it was functional so that is what I use.
Touring where I use a 36T chainring on the inner position on a double crank, I use a 44T chainring as a bashguard because if I conclude that the 36 is too low, I can add a few links to the chain and use the 44 instead. But it looks a bit odd to have two chainrings and no front derailleur.
If you have a chainring in the outer position on a Rohloff bike and move that chainring to an inner position, that will change your chainline a bit. My chainline is off about 5mm because I run my chain on a chainring on the inner postion, but my chainline would be perfect if I had the chainring in the outer position. I see a 5mm out of line position as not a problem, but I have no clue what you have on your bike.