Steve, have you considered fitting a Rohloff hub gearbox to your wife's bike? It has 14 usable gears, spaced about 13% apart, 526% range, and can be geared as low as she can keep her balance; we have some stump-puller transmissions on the forum here. Personally, for a tourer (and for a utility bike and a commuter for that matter) I consider a Rohloff a better first option, with fewer limiting factors, than going straight to an electrified bike.
If a Rohloff is out of the reckoning, I'll answer your questions:
First of all, forget anything but the 250W* motor. With a bigger motor comes a bigger battery consumption (or less range), more weight that has to be dragged along. Secondly, borrow or rent an electric bike to ascertain if your wife will be happy pedalling along the extra weight when the motor is not in use. If you fit a 750W motor, your wife will have to drag a battery three times as large, and sooner or later the police will take an interest. And forget about 25mph too; sure, I've ridden up there on occasion, but I have an humongous battery, and I'm never further than 20-25kph from home unless I know that I'll sleep next to a plug that night. The other number Anto threw out, averaging 13, is good, but it is 13-15kph not mph, which is what my pedal pals and I average over the course of a year (we live in countryside that is all hills, all the time -- the few pieces of flat roads carry lethal amounts of traffic at lethal speed, and the hard shoulder, or any shoulder, keeps disappearing). You have to approach electrifying a bike realistically, even humbly; it just isn't a roadracer's option, which is what Anto appears to think!
The Bafang BB motor generally comes with a 46T chainring but that isn't set in stone; maybe your supplier will swap it out for you. In any case, a different tooth-count chainring is under a tenner from China, and, since it is steel, you'll never wear it out. I have a 44T chainring on my bike, which appears to me to be the smallest the Bafang BB motor will take that will also suit a Chainglider, an amenity I insist on on all my bikes. The chainring is dished to claw back tread width, so if you want another type of chainring, it could be an expensive custom job; some ali chainrings are available but while the Italian ones are beautiful, they're also about a fifth of the price of the complete kit. I'm well satisfied with the steel chainring (it's 20 years since I last bothered with a fast-wearing ali chainring). Before I fitted the centre motor my transmission was 38x16T (I in the middle of a couple of rounds of heart surgery), and I thought that I would use the motor more because of the 44T chainring, but that hasn't happened and the longer legs have turned into a good thing for my health too.
If your wife cannot or does not want to pull a 46 or 44T chainring, there's an alternative that lets her keep her entire transmission, including the front derailleur: front hub drive. If that means she loses her hub dynamo, you can get B&M front and rear lamps that operate off the motor battery (36V nominal). See
http://coolmainpress.com/BICYCLINGbuildingpedelec5.html The front motor I had was the Bafang QSWXK and you can see here how I fitted it:
http://coolmainpress.com/BICYCLINGbuildingpedelec1.html It comes as a full kit including an excellent battery, well-scaled to the motor, from the vendor I recommend. A complete installation of the front motor, including new lamps, came out a third cheaper than the centre motor installation, in both cases including the battery. The front motor needs a bit more care than the centre motor: I burned mine out in 3500km, but my bike carries more weight -- my painting gear is on it all the time -- than most fast tourers would contemplate, and I have a heavy throttle thumb. It was rebuildable but I bought it only as an experiment, so I didn't bother, just went straight for a centre motor better scaled to my requirements and habits, which has now exceeded the mileage of the front motor without any sign of stress. For a motor to last a very long time, you may wish to swap out the nylon gears for the available and pretty cheap steel gears.
I've no idea how the kit brake levers compare with the Thorn-supplied brake lever; I just left those brake levers in the box because I bought special hydraulic brake interrupters.
* And forget what an electrical engineer knows about the relationship of Watt to horsepower etc. The CE regulations allow the manufacturer to say how strong the motor is, and nobody checks on it. As an associated fact: These Bafang motors are so popular because of their heritage, their origins in the famous offroad BPM motor, which started at about a real 350W but was optimized for torque and so "appeared" to be a 250W motor. Torque is by far more useful than Watt as a measure of the utility of a motor for a tourer's bike. Watt is useful only for the speed freaks.