this is a new one on me,i taught the adjuster screws on the rear mech were for that purpose
Jags,
It is all about how the upper run of chain approaches the chainring through the rear of the front derailleur *and* about chainstay clearance. With rear-suspended MTBs, the swingarm pivots through a range of motion, where on a road bike the rear wheel/chainstays are frigid. The angle rating on the front derailleur is to ensure proper shifting by having the chain pass the little bumps formed into the inner cage plate.
Chris showed a lot of foresight in checking.
There's a different but also important factor to watch for with front derailleurs, wrt mixing road and MTB drivetrain components: Chainwheel sizing. Using a road bike front mech (say, sized for a 52T chainring) on a compact MTB triple (with, say, a 44T outer 'ring), the rear of the road mech will hang out a in space, making shifting a bit lazy. Go the other way and fit a compact MTB triple to a large outer'ring and the cage contour won't match the 'ring very well.
I prefer half-step and granny gearing, but it has become tougher over the years to find a suitable front mech. Indexed chanring setups are all maximized for crossover gearing, and use front derailleurs with a deep inner cage plate. These foul the side of the middle 'ring on upshifts when used with a half-step. Just one more thing to watch for if you deviate from the narrow path of drivetrains engineered to work as "systems".
Best,
Dan.