HI Peter,
I will try and help with what experiences I have had with paint and this may help in your decision to make a choice on colour and paint type.
I have used many types of paint in the past for varying jobs and purposes including bikes, cars, industrial equipment etc.. and each paint has its own niche.
I have recently sprayed the wife's bonnet wings and grill due to a rather large object being in the way ie:
another car!!!!
This was using Lechler single pack BSB base coat and a single pack lacquer which has turned out fantastic. Ive also has the experience of using two pack paint which is even better in its results and application although time is of the essence with this type of paint, the durability of paint is vast from type to type but also similar to same due to whom ever has mixed it how it was cured and finally finished.
If you were to look at a chart of differing manufactures of the same type of paint you would see a vast amount of difference in paint hardness , the German made automotive trade uses a very hard finish which although promoted durability to the highest it, it is very difficult to remove imperfections using conventional buffing techniques, conversely people like Honda use a very soft finish paint which scratches and marrs very easily but is easy to correct.
Urethane paint and its derivatives polyurethane are very good paints in their own right for the purpose they serve along with enamel , which can also come under the same umbrella as the enamel in name terminology.
Enamel has become known to be very ornate and takes a very high gloss shine to its finish, with admirable durability. Powder coating which is what is used on the thorn bikes has certainly proved to me to be very durable much like the German paint that I referred to earlier, although as I suggested in my earlier post I have had my problems with it delaminating from the base coat around the seat post area, my fix for that was to put a single pack lacquer around the area and blend this in with a hand paste later, much like t-cut but much better.
I too have tried to expand my knowledge with regards to pigment amount and colour in terms of what can be expected back from its longevity and to no avail do I have anything positive to add, albeit that I have not ever come across anything to suggest otherwise, so I will keep looking out for that one.
Given the knowledge that I have had over the years with paint and the different options that are out there I would go for a powder coat finish with heavy clearcoat on top, this style of covering I have also found easy to airbrush Bsb base coat and single pack lacquer over as i have done a few times now on my expr which is finished in ivory and deep black billiard Que.