Let's discuss pressures.
More in the rear?
If a loaded bike is unbalanced, tyre pressure differentials won't fix the problem and could as easily aggravate it. You need to stop and redistribute the load.
On an unloaded bike, except for the rider, substantially higher pressure in the rear than the front may sharpen up the handling of your bike, especially if you start with a well-pressured front tyre.
But I must tell you that I wouldn't dream of doing it. My daily bike has a very long wheelbase and 60mm fat tackles operated at the minimum pressure that doesn't lead to constant fishbites, and the behaviour may seem sluggish to someone used to a short wheelbase, thin-high-pressure-tired road bike. It's like moving from a little English sports car to a V12 Mercedes. I have a good deal of experience developing racing car suspensions, in which the tyre and its pressure is your first line of defence, and I know for a fact that a bit of understeer is its own very handy safety margin, especially when the rider doesn't want a broken hip. The faster my bike goes, alas only on the downhills these days, the more valuable the security that flows from the understeer becomes. Rough roads? The roads here are an embarrassment, and the lanes more so, but nothing throws my bike off line, though road bikers who arrive at the bottom of the hill considerably after me are white around the gills and worried about the integrity of their bikes.
Setting the bike up razor-sharp, even with big boots, is no problem, practically speaking. But the desirability of such an action is in deep doubt. And most of the modern touring tyres that find favour with forum members (all the ones with Marathon in the name, for starters) are intended to be used as balloons or semi-balloons, with low tyre pressures. Pumping them harder to get twitchy handling seems to me counterproductive.
The behaviour of a sharp bike at high speed won't impress you. First of all, it's not a relaxing touring ride, it's a Sundays-only speed-freak bike. You have to be on top of a nervous bike all the time or it will throw you into the gorse, because a quick steering is a positive feedback system in which whatever goes wrong gets magnified, and even a twig on the road can throw you off, whereas my bike rides right across potholes that will bend the rims on racing bikes. A neutral-handling bike (roadholding is the bike keeping the rubber on the road, handling is its ability to recover from upsets) is even worse, in that you don't know which way it will break, and half the time you will be bracing in the wrong direction, and make things worse, perhaps to take a spill.
You can try this for yourself. If you're following the official recommendations of low pressure encapsulated in an essay by Mr Blance a couple of years ago, and you have good wide tyres, pump the front tyre to about 20psi under its limit, and the rear tyre to only 5psi under its limit. Notice how much of your comfort these changes have consumed. Ride down a hill with sweeping curves at a moderate pace, riding the brakes if necessary. Notice how the bike wants to turn to the insides of corners, as if the road is much more steeply cambered than you can see is the reality, and that you have to expend considerably more effort to keep the bike tracking with the road, and out of the ditch. You can aggravate this effect by putting a smoothly worn tyre on the back to give it even better grip. You can detune the effect too, by letting air our of the rear tyre to bring the tyre pressures closer together.
I take no responsibility for any outcomes of such experiments by any readers. Read the bit again where I say, "I wouldn't dream of doing it."